In present scenario biodiesel has
been accepted as clean alternative fuel by most of the developed
& developing countries.
Countries like USA, France, Germany, Italy, Malaysia, Czechoslovakia,Austria
& other European & Asian countries have put a major thrust
on production of biofuel from vegetable oil through extensive research
& development. Biofuel can be used as fuel for diesel engines
(as either B5-a blend of 5% biodiesel for High speed diesel or B20
or B100). Brazil uses ethanol as 100% fuel in about 20% of vehicles
& 25% blend with gasoline in the rest of the vehicles. USA uses
10% ethanol-gasoline blends whereas a 5% blend is used in Sweden
& Australia.India is no exception. Extensive experimentation
by Ministry of Non-conventional Energy source. |
 |
| Indian Oil Co., Mahindra
& Mahindra & other private entrepreneurs through their research
& studies had demonstrated that Jatropha & Karanja oil could
be a low cost appropriate feed stock for production of biofuel in
the operation of Diesel Engines. In recent times, Indian Railways
have successfully tested biofuel produced from Jatropha Oil blended
(10%) with petrodiesel. |
What
is Biodiesel?
Biodiesel is an alternative fuel similar to conventional or "fossil"
diesel. Biodiesel meets most of chemical /physical standard of petrodiesel
& being plant based, it does not emit sulphur/CO on burnllig
& are non-toxic, non-polluting, bio-degradable & environment
friendly. With no sulphurdioxide emission & unbumt hydro-carbons,
biodiesel is an ideal fuel for heavily polluted cities. Biodiesel
derived from the tree bourne oil & fats of plants like Jatropha
curcas, Sunflower, Rapeseeds, Palm, Karanj ect. Can be used as a
substitute or an additive to petrodiesel. Biodiesel can also be
processed from animal fats & used vegetable oils. As an alternative
fuel, biodiesel can provide power similar to conventional petrodiesel
& this can be used safely in diesel engines without any modification
of the currently used diesel engines. Like Mercedez, Daimler Chrysler
& other renowned Automobile manufacturers like Mahindra &
Mahindra, Tata Motors in India have by now extended the engine warranty
on use of biodiesel in their vehicle. |
Description
of Biodiesel & it’s uses:
The proposed product to be made in OUR plant is BioDiesel.
Biodiesel is a domestically produced, renewable fuel that can be
manufactured from vegetable oils, animal fats, or recycled restaurant
oils. Biodiesel is safe, biodegradable, and reduces serious air
pollutants such as particulate matter, carbon monoxide, hydrocarbons,
and toxic chemicals. Blends of 20% biodiesel with 80% petroleum
diesel (B20) is generally used in unmodified diesel engines. Biodiesel
can also be used in its pure form (B100).
Biodiesel (fatty acid alkyl esters) is a cleaner-burning diesel
replacement fuel made from natural, renewable sources such as new
and used or non-edible vegetable oils. Just like petroleum diesel,
biodiesel operates in compression ignition engines.
Using biodiesel in a conventional diesel engine substantially reduces
emissions of unburned hydrocarbons, carbon monoxide,sulfates,polycyclic
aromatic hydrocarbons,nitrated polycyclic aromatic hydrocarbons,
and particulate matter.
These reductions increase as the amount of biodiesel blended into
diesel fuel increases. The best emissions reductions are seen with
B100. The use of biodiesel decreases the solid carbon fraction of
particulate matter (since the oxygen in biodiesel enables more complete
combustion to CO2) and reduces the sulfate fraction (biodiesel contains
less than 24 ppm sulfur), while the soluble, or hydrocarbon, fraction
stays the same or increases. Therefore, biodiesel works well with
new technologies such as diesel oxidation catalysts (which reduce
the soluble fraction of diesel particulate but not the solid carbon
fraction).
Emissions of nitrogen oxides increase with the concentration of
biodiesel in the fuel. Some biodiesel produces more nitrogen oxides
than others and some additives have shown promise in modifying the
increases. More R&D is needed to resolve this issue.
Biodiesel has physical properties very similar to conventional diesel.
|
Biodiesel's
Physical Characteristics:
| Specific
gravity |
0.87
to 0.89 |
| Kinematic
viscosity @ 40°C |
3.7 to
5.8 |
| Cetane
number |
46 to
70 |
| Higher
heating value (btu/lb) |
16,928
to 17,996 |
| Sulfur,
wt% |
0.0 to
0.0024 |
| Cloud
point °C |
-11
to 16 |
| Pour
point °C |
-15 to
13 |
| Iodine
number |
60 to
135 |
| Lower
heating value (btu/lb) |
15,700
to 16,735 |
Biodiesel is packed in 35 kg carboys,
225 kg MS Barrels and Bulk in Tankers. |
How is Biodiesel
Made?
Biodiesel fuel can be made from new, used or non-edible vegetable
oils, which are non-toxic, biodegradable, renewable resources. Oils
are chemically reacted with methanol to produce chemical compounds
known as fatty acid methyl esters. Biodiesel is the name given to
these esters when they are intended for use as fuel. Glycerol (used
in pharmaceuticals and cosmetics, among other markets) is produced
as a co-product.
Biodiesel can be produced by a variety of esterification technologies.
The oils are filtered and preprocessed to remove water and contaminants.
If free fatty acids are present, they can be removed or transformed
into biodiesel using special pretreatment technologies. The pretreated
oils are then mixed with methanol and a catalyst (usually potassium
hydroxide). The oil molecules(triglycerides) are broken apart
and reformed into esters and glycerol, which are then separated
from each other and purified.
Approximately 55% of the biodiesel industry can use any oil feedstock,
including recycled cooking oils. The other half of the industry
is limited to vegetable oils the least expensive of which is jatropha
oil. The jatropha oil industry has been the driving force behind
biodiesel commercialization in India because of large production
capacity, product surpluses, and declining prices. Similar
issues apply to the recycled oils industry, even though these
feedstock are less expensive than jatropha oils. |
Biodiesel
Benefits and it's Limitations:
1. Biodiesel is a substitute or extender for traditional petroleum
diesel and you don't need special pumps or high pressure equipment
for fueling. In addition, it can be used in conventional diesel
engines, so you don't need to buy special vehicles or engines to
run biodiesel.
2. Scientists believe carbon dioxide is one of the main greenhouse
gases contributing to global warming. Pure biodiesel (100 percent
biodiesel) reduces carbon dioxide emissions by more than 75 percent
over petroleum diesel. Using a blend of 20 percent biodiesel reduces
carbon dioxide emissions by 15 percent.
3. Biodiesel also produces fewer particulate, carbon monoxide, and
sulfur dioxide emissions, all targeted as public health risks by
the Environmental Protection Agency. Biodiesel contains only trace
amounts of sulfur, typically less than the new EPA standards that
will go into effect in 2006 for diesel fuel.
4. Since biodiesel can be used in conventional diesel engines, the
renewable fuel can directly replace petroleum products; reducing
the country's dependence on imported oil.
5. Biodiesel offers safety benefits over petroleum diesel because
it is much less combustible, with a flash point greater than 150°C,
compared to 77°C for petroleum diesel. It is safe to handle,
transport, and store, and has a higher flash point than petroleum
diesel. It can also be stored in diesel tanks and pumped with regular
equipment except in colder weather, where tank heaters or agitators
may be required.
6. Biodiesel mixes readily with petroleum diesel at any blend level,
making it a very flexible fuel additive.
7. Biodiesel is an oxygenated fuel, so it contributes to a more
complete fuel burn and a greatly improved emissions profile. The
more biodiesel used in a blend, the higher the emission reductions.
One of the unique benefits of biodiesel is that it significantly
reduces air toxic that are associated with petroleum diesel exhaust
and are suspected of causing cancer and other human health problems.
NOx emissions are an exception to the rule, since biodiesel tends
to increase NOx emissions. Recent research has shown a number of
ways
to mitigate this problem.
You can use biodiesel in most engines made after 1994
with some limitations:
Engine performance (fuel economy, torque, and power)
is less than that of diesel by 8% to 15%, because of the lower
energy content of the biodiesel (121,000 Btu compared to 135,000
Btu for diesel fuel).
Engine performance with B20 is virtually the same as with petroleum
diesel.
Problems associated with storage, seals and gaskets, are minimal.
Even very low amounts of biodiesel (1% to 2%) can provide substantial
lubricity benefits to premium diesel fuels.
Every liter of biodiesel replaces 0.95 liter of petroleum-based
diesel over its life cycle. It is also very energy efficient.
For every unit of fossil energy used to produce biodiesel, 3.37
units of biodiesel energy are created.
Additionally, biodiesel reduces the amount of carbon dioxide (CO2)
being released into the atmosphere. It releases less fossil CO2
than does conventional diesel, and the crops used to produce biodiesel
absorb large amounts of CO2 as they grow. And because biodiesel
is nontoxic and biodegradable, it is an excellent fuel for use
in fragile environments such as estuaries, lakes, rivers,nd national
parks. |
Applications
It is commonly used as fuel for stationary diesel engine
like Pump sets and other agricultural implements and also in Diesel
cars.
The most important factor in production of BIODIESEL is meeting
the National & International standards set for Biodiesel. This
is where the crux and importance of the Process Technology and Equipment
design lies. This should be well understood by all concerned before
selecting the processing plants and the brains behind.
Standards
Pure biodiesel (B100) needs to meet the requirements of
ASTM D6751 to avoid engine operational problems.
| ASTM
D-6751 standards for biodiesel |
| Flash
point (closed cup) |
130°C
min. (150°C average) |
| Water
and sediment |
0.050%
by vol., max. |
| Kinematic
viscosity at 40°C |
1.9-6.0
mm2/s |
| Ramsbottom
carbon residue, % mass |
0.10
|
| Sulfated
ash |
0.020%
by mass, max. |
Sulfur
|
0.05%
by mass, max. |
| Copper
strip corrosion |
No. 3
max |
Cetane
|
47 min.
|
| Carbon
residue |
0.050%
by mass, max. |
Acid
number -- mg KOH/g |
0.80
max. |
| Free
glycerin |
0.020
% mass |
Total
glycerine (free glycerine
and unconverted glycerides
combined) |
0.240%
by mass, max. |
| Phosphorus
content |
0.001
max. % mass |
| Distillation
|
90% @
360°C |
|
Transport information
Safe for air, sea and road freight. As good or as bad as mineral
Diesel.
Personal protection
Sfety glasses, adequate ventilation. Water wash and Shower bath.Biodiesel
is not a hazardous compound but during the operation of the process,
operators are suggested to take precautions as in any other chemical
and pharmaceutical plants. Consumer Safety
BioDiesel is used as substitute for Diesel and all safety precautions
are same as that of Petroleum diesel.
Alternative Fuels Incentives and Laws
These are being formulated. In fact a national biodiesel policy
is awaited where there is supposed to be many concessions for this
industry.
Biodiesel is plant based oil processed from TBO (Tree borne oil)
that is oil seeds of various plants such as Soyabean,Sunflower,Rapeseed,Ground
nut,Palm,Neem,Karanj and even from Animal fats like Lard,Tallow
and other fats and oils.
Keepig with the KYOTO PROTOCOL,GLOBAL WARMING & ENVIRONMENTAL
PROTECTION issues and shortages of mineral fuels,skyrocketing Crude
oil prices ,a global revolution has started in production of ECO
FRIENDLY ENERGY such as ELECTRICITY from wind mills & Hydel
power or bio gas based power generation plants,SOLAR ENERGY,HYDROGEN
CELLS, FUEL OILS to Replace PETROL & DIESEL through production
of BIO ETHANOL & BIODIESEL.
In India,we are already using PETROL doped with 5% ETHANOL from
2003 and the ultimate aim is to go for ETHANOL blends upto 20% by
2012.Likewise,all mineral diesel used by INDIAN RAILWAYS,STATE
TRANSPORTS,POWER GENERATING PLANTS,and ALL OTHER INDUSTRY will be
using upto a blend of 20% BIODIESEL by 2012 and ultimate aim is
to completely replace MINERAL DIESEL in due course.Requirement of
BIODIESEL,therefore,is HUGE- potential is immense. |
Sources of Biodiesel
Production &
Technology
Buy Biodiesel
Reactor
Global Warming &
Pollution |
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